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Spherical structures exhibit exceptional stability by minimizing surface tension. As artificially synthesized functional spherical materials, nanoparticles boast a large specific surface area and high surface energy. Their surface properties are of paramount importance for applications in biomedical, catalytic, and environmental sectors. Nevertheless, owing to their extremely small size and structural ambiguities, traditional analytical techniques find it challenging to clearly ascertain information regarding their surface adsorption behavior. Spherical nanoclusters, which possess atomic-level precise structures and serve as molecular models for nanoparticles, show great potential in resolving this problem. However, they currently encounter several obstacles.
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